Origin of K-rich diamond-forming immiscible melts and CO2 fluid via partial melting of carbonated pelites at a depth of 180–200 km     

《Gondwana Research》2019

Melt inclusions in kimberlitic and metamorphic diamonds worldwide range in composition from potassic aluminosilicate to alkali-rich carbonatitic and their low-temperature derivative, a saline high-density fluid (HDF). The discovery of CO₂ inclusions in diamonds containing eclogitic minerals are also essential. These melts and HDFs may be responsible for diamond formation and metasomatic alteration of mantle rocks since the late Archean to Phanerozoic. Although a genetic link between these melts and fluids was suggested, their origin is still highly uncertain. Here we present experimental results on melting phase relations in a carbonated pelite at 6 GPa and 900–1500 °C. We found that just below solidus K₂O enters potassium feldspar or K₂TiSi₃O₉ wadeite coexisting with clinopyroxene, garnet, kyanite, coesite, and dolomite. The potassium phases react with dolomite to produce garnet, kyanite, coesite, and potassic dolomitic melt, 40(K_0.90Na_0.10)₂CO₃·60Ca_0.55Mg_0.24Fe_0.21CO₃ + 1.9 mol% SiO₂ + 0.7 mol% TiO₂ + 1.4 mol% Al₂O₃ at the solidus established near 1000 °C. Molecular CO₂ liberates at 1100 °C. Potassic aluminosilicate melt appears in addition to carbonatite melt at 1200 °C. This melt contains (mol/wt%): SiO₂ = 57.0/52.4, TiO₂ = 1.8/2.3, Al₂O₃ = 8.5/13.0, FeO = 1.4/1.6, MgO = 1.9/1.2, CaO = 3.8/3.2, Na₂O = 3.2/3.0, K₂O = 10.5/15.2, CO₂ = 12.0/8.0, while carbonatite melt can be approximated as 24(K_0.81Na_0.19)₂CO₃·76Ca_0.59Mg_0.21Fe_0.20CO₃ + 3.0 mol% SiO₂ + 1.6 mol% TiO₂ + 1.4 mol% Al₂O₃. Both melts remain stable to at least 1500 °C coexisting with CO₂ fluid and residual eclogite assemblage consisting of K-rich omphacite (0.4–1.5 wt% K₂O), almandine-pyrope-grossular garnet, kyanite, and coesite. The obtained immiscible alkali‑carbonatitic and potassic aluminosilicate melts resemble compositions of melt inclusions in diamonds worldwide. Thus, these melts entrapped by diamonds could be derived by partial melting of the carbonated material of the continental crust subducted down to 180–200 km depths. Given the high solubility of chlorides and water in both carbonate and aluminosilicate melts inferred in previous experiments, the saline end-member, brine, could evolve from potassic carbonatitic and/or silicic melts by fractionation of Ca-Mg carbonates/eclogitic minerals and accumulation of alkalis, chlorine and water in the residual low-temperature supercritical fluid. Direct extraction from the hydrated marine sediments under conditions of cold subduction would be another possibility for the brine formation.  相似文献   

Using Models of the Deep Structure of the Earth’s Crust and Upper Mantle Based on GOCE Gravity Data in Metallogenic Analysis     

Volkov  A. V.  Galyamov  A. L.  Savchuk  Yu. S. 《Izvestiya Atmospheric and Oceanic Physics》2020,56(12):1528-1536

Izvestiya, Atmospheric and Oceanic Physics - Gravimetric data obtained by the GOCE spacecraft contributes to the development of global models of the deep structure of the Earth’s crust and...  相似文献   

Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites          下载免费PDF全文

Nao Nakanishi  Tetsuya Yokoyama  Satoki Okabayashi  Tomohiro Usui  Hikaru Iwamori 《Meteoritics & planetary science》2018,53(5):1051-1065

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.  相似文献   

SPATIAL—TEMPORAL VARIATION OF HEAVY METAL ELEMENTS CONTENT IN COVERING SPIL OF RECLAMATION AREA IN FUSHUN COAL MINE     

YUJun－bao  LIUJing－shuang 《中国地理科学(英文版)》2002,12(3):268-272

Grid method is employed for sampling covering soil at the test field,which is reclamation area filled by coal mining wastes for cropland in the Fushun coal mine,Liaoning Province,the Northeast China.The soil samples are taken at different locations,including three kinds of covering soil,three different depths of soil layers and four different covering ages of covering soil.The spatial-temporal variation of heavy metal element content in reclamation soil is stud-ied.The results indicate that the content of heavy metal elements is decreasing year after year,the determinant reason why the content of heavy metal elements at 60cm depth layer is higher than that at 30cm depth layer and surface is fertiliz-er and manure application;the metal elements mainly come from external environment;there is no metal pollution coming from mother material (coal mining wastes)in plough layer of covering soil.  相似文献   

Comet nuclei: Morphology and implied processes of surface modification     

A.T. Basilevsky  H.U. Keller 《Planetary and Space Science》2006,54(8):808-829

Surface morphology and related issues for nuclei of three comets: Halley, Borrelly and Wild 2, are considered in the paper. Joint consideration of publications and results of our analysis of the comets’ images led to conclusions, partly new, partly repeating conclusions published by other researchers. It was found that typical for all three nuclei is the presence of rather flat areas: floors of craters and other depressions, mesas and terraces. This implies that flattening surfaces or planation is a process typical for the comet nuclei. Planation seems to work through the sublimation-driven slope collapse and retreat. This requires effective sublimation so this process should work only when a comet is close to the Sun and if on the nucleus there are starting slopes, steep and high enough to support the “long-distance” avalanching of the collapsing material. If the surface had no starting slopes, then instead of planation, the formation of pitted-and-hilly surfaces should occur. An example of this could be the mottled terrain of the Borelly nucleus. Both ways of the sublimational evolution on the nucleus surface should lead to accumulation of cometary regolith. The thickness of the degassed regolith is not known, but it is obvious that in surface depressions, including the flat-floor ones, it should be larger compared with nondepression areas. This may have implications for the in situ study of comets by the Deep Impact and Rosetta missions.Our morphological analysis puts constraints on the applicability of the popular “rubble-pile comet nucleus” hypothesis (Weissman, 1986. Are cometery nuclei primordial rubble piles? Nature 320, 242-244.). We believe that the rubble pile hypothesis can be applicable to the blocky Halley nucleus. The Borelly and Wild 2 nuclei also could be rubble piles. But in these cases the “rubbles” have to be either smaller than 30-50 m (a requirement to keep lineament geometry close to ideal), or larger than 1-2 km (a requirement to form the rather extended smooth, flat surfaces of mesa tops and crater floors). Another option is that the Borelly and Wild 2 nuclei are not rubble piles.In relation to surface morphology we suggest that three end-member types of the comet nuclei may exist: (1) impact cratered “pristine” bodies, (2) non-cratered fragments of catastrophic disruption, and (3) highly Sun-ablated bodies. In this threefold classification, the Wild 2 nucleus is partially ablated primarily cratered body. Borrelly is significantly ablated and could be either primarily cratered or not-cratered fragment. Halley is certainly partially ablated but with the available images it is difficult to say if remnants of impact craters do exist on it.Recently published observations and early results of analysis of the Tempel 1 nucleus images taken by Deep Impact mission are in agreement with our conclusions on the processes responsible for the Halley, Borrelly and Wild 2 nuclei morphologies. In particular, we have now more grounds to suggest that decrease in crater numbers and increase of the role of smooth flat surfaces in the sequence Wild 2?Tempel 1?Borelli reflects a progress in the sublimational degradation of the nucleus surface during comet passages close to the Sun.  相似文献   

Fatty acid composition of surface sediments in the subtropical Pearl River estuary and adjacent shelf,Southern China     

《Estuarine, Coastal and Shelf Science》2006,66(1-2):346-356

Surface sediments (10 cm) of the subtropical Pearl River estuary and adjacent shelf, Southern China were collected. Fatty acids and compound-specific carbon isotopic analyses were determined to infer their sources and biogeochemical cycle of this lipid in the subtropical Pearl River estuary and adjacent northern South China Sea (SCS). The total concentrations of fatty acids ranged from ∼1.28 to ∼42.25 μg g⁻¹ dry weight. The levels of polyunsaturated fatty acids (PUFA) were low (0.2–4.8% of total fatty acids), suggesting that fatty acids derived from algae were effectively recycled during the whole settling and depositing process. Bacterial fatty acids were significantly high and terrigenous fatty acids were low in the sediments. Principal component analysis (PCA) of the data also indicates that a clear separation of the biogeochemical sources can be seen. The δ¹³C values of bacterial fatty acids, i.e., i/aiC₁₅ (−22.9‰ to −29.4‰) suggest that bacteria within the sediments mainly utilize a labile pool of organic matter derived from algae for their growth in the subtropical Pearl River estuary system.  相似文献   

Origin of fluids responsible for the formation of Au-bearing rodingites based on isotope data: Evidence from the Karabash Alpine-type Ultramafic Massif, the southern Urals     

V. V. Murzin 《Doklady Earth Sciences》2006,407(1):254-257

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The process and driving forces of eco-geo-environmental evolution of the Songnen Plain in northeast China since the Quaternary     

Dianfa Zhang  S. Wang 《Environmental Geology》2001,40(11-12):1362-1366

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Himalayan magmatism and porphyry copper–molybdenum mineralization in the Yulong ore belt, East Tibet     

X. X. Gu  J. X. Tang  C. S. Wang  J. P. Chen  B. B. He 《Mineralogy and Petrology》2003,78(1-2):1-20

Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 10⁶ tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002  相似文献   

International Conference on Continental Volcanism—IAVCEI 2006     

Yigang Xu Martin A Menzies 《《幕》》2006,29(3):204-206

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